Genesis 4:22
And Zillah, she also bore Tubalcain, an instructor of every artificer in brass and iron: and the sister of Tubalcain was Naamah.
Torrey's Topical Textbook—AKJV

1 Samuel 13:19
Now there was no smith found throughout all the land of Israel: for the Philistines said, Lest the Hebrews make them swords or spears:
Torrey's Topical Textbook—AKJV