Genesis 4:22
And Zillah, she also bore Tubalcain, an instructor of every artificer in brass and iron: and the sister of Tubalcain was Naamah.
Torrey's Topical Textbook—AKJV

2 Timothy 4:14
Alexander the coppersmith did me much evil: the Lord reward him according to his works:
Torrey's Topical Textbook—AKJV